4. The Hamiltonian for the rotational energy of a diatomic mole... | Filo
4. The Hamiltonian for the rotational energy of a diatomic mole... | Filo
5.1K viewsMar 23, 2024
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A diatomic molecule can be modeled as a rigid rotor with moment of inertia I and an electric dipole moment d along the axis of the rotor. The rotor is constrained to rotate in a plane, and a weak uniform electric field & lies in the plane. Write the classical Hamiltonian for the rotor, and find the unperturbed energy levels by quantizing the angular-momentum operator. Then treat the electric field as a perturbation, and find the first nonvanishing corrections to the energy levels. | Numerade
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