Angelina Jolie once opened up about how important charity work has been in her life ever since she started traveling the world.

James, 51 - who infamously kissed Angelina on the lips at the 2000 Oscars - secretly exchanged vows with Romi this past ...

From his breakout role on 'Dawson's Creek' to parenting six children, look back at some of the actor's biggest moments ...